Publications

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17. Cobalt-Catalyzed and Lewis Acid-Assisted Nitrile Hydrogenation to Primary Amines: A Combined Effort Tokmic, K., Jackson, J. B., Salazar, A., Woods, T. J., and Fout, A. R. J. Am. Chem. Soc. Articals ASAP.


16. Synthesis and Characterization of Bidentate NHC-CAryl Nickel(II) Complexes: Isocyanide Insertion To Form NHC-η2-iminoacyl Complexes Nugent, J.W., Espinosa-Martinez, G., Gray, D. L., and Fout, A. R. Organometallics 2017, 36, 2987-2995.




15. Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles Ibrahim, A.D., Entsminger S., and Fout, A. R. ACS Catal. 2017, 6 , 3730–3734.


14. Tuning the Fe(II/III) Redox Potential in Nonheme Fe(II)−Hydroxo Complexes through Primary and Secondary Coordination Sphere Modifications Gordon, Z., Drummond, M. J., Matson, E. M., Bogart, J. A., Schleter, E. J., Lord, R. L., and Fout, A. R. Inorg. Chem. 2017, Article ASAP


13. A bioinspired iron catalyst for nitrate and perchlorate reduction Ford, C., Park, Y. J., Matson, E. M., Gordon, Z., and Fout, A. R. Science 2016, 354, 741-743. Abstract Reprint Full Print


12. Alkyne Semihydrogenation with a Well-Defined Nonclassical Co–H2 Catalyst: A H2Spin on Isomerization and E-Selectivity Tokmic, K., and Fout, A. R. J. Am. Chem. Soc. 2016, 138, 13700-13705.


11. Well-Defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence for a Co(I)/Co(III) Redox Process in Olefin Hydrogenation Tokmic, K., Markus, C.R., Zhu, L., and Fout, A.R. J. Am. Chem. Soc. 2016, 138, 11907-11913.




10. A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes Ibrahim, A.D., Entsminger, S.W., Zhu, L., and Fout, A.R. ACS Catal. 2016, 6 , 3589-3593.


9. Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates Espinosa-Martinez, G., Ocampo, C., Park, Y.J., and Fout, A.R. J. Am. Chem. Soc. 2016, 138, 4290-4293.


8. Monoanionic bis(carbene) pincer complexes featuring cobalt(I–III) oxidation states. Ibrahim, A. D., Tokmic, K., Brennan, M. R., Kim, D., Matson, E. M., Nilges, M. J., Berkte, J. A., and Fout, A. R. Dalt. Trans. 2016, 45, 9805-9811.


7. Synthesis and characterization of M(II) (M = Mn, Fe and Co) azafulvene Complexes and their X3 − Derivatives. Matson, E.M., Park, Y.J., Bertke, J.A., and Fout, A.R. Dalt. Trans. 2015, 10377-10384.


6. Exploring Mn–O bonding in the context of an electronically flexible secondary coordination sphere: synthesis of a Mn(III)–oxo. Park, Y.J., Matson, E.M., Nilges, M.J., and Fout, A.R. Chem. Commun. 2015, 5310–5313.


5. Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo.Matson, E.M., Park, Y.J., and Fout A.R. J. Am. Chem. Soc. 2014, 17398–17401.


4. Meridional vs. facial coordination geometries of a dipodal ligand framework featuring a secondary coordination sphere.Matson, E.M., Gordon, Z., Lin, B., Nilges M.J., and Fout, A.R. Dalt. Trans. 2014, 16992-16995.


3. Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C−H Bond to Form a Ni(II) Hydride Matson, E. M.; Espinosa-Martinez, G.; Ibrahim, A. D.; Jackson, B. J.; Bertke, J. A.; Fout, A. R. Organometallics 2015, 399-407.


2. A Synthetic and Mechanistic Investigation into the Cobalt(I) Catalyzed Amination of Aryl Halides Brennan, M. R.; Kim, D.; Fout, A. R. Chem. Sci. 2014, 5, 4831-4839.


1. Isolation of Iron(II) Aqua and Hydroxyl Complexes Featuring a Tripodal H-bond Donor and Acceptor Ligand Matson, E. M.; Bertke, J. A.; Fout, A. R. Inorg. Chem. 2014, 53, 4450-4458.


Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters. Powers, T. M.; Gu, N. X.; Fout, A. R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc. 2013, 135, 1448-14458.

Understanding intermolecular C−F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and [2+2]-cycloadditon/β-fluoride elimination. Fan, H.; Fout, A. R.; Bailey, B. C.; Pink, M.; Baik, M.-H.; Mindiola, D. J. Dalton Trans. 2013, 42, 4163-4174.

Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic and Computational Investigation into the Correlation of Molecular and Electronic Structure. Fout, A. R.; Xiao, D. J.; Zhao, Q.; Harris, T. D.; King, E. R.; Eames, E. V.; Zheng, S.-L.; Betley, T. A. Inorg. Chem. 2012, 51, 10290-10299.

1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the C−F bond activation pathway and rotation of the titanium alkylidene moiety. Andino, J. G.; Fan, H.; Fout, A. R.; Bailey, B. C.; Baik, M.-H.; Mindiola, D. J. J. Organomet. Chem. 2011, 696, 4138-4146.

Oxidative Group Transfer to a Trimanganese Complex to Form an Interstitial μ6-nitride and μ6-oxide, [Mn66-E)]n-. Fout, A. R.; Zhao, Q.; Xiao, D. J.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 16750-16753.

1,2-CF Bond Activation of Perfluoroarenes and Alkylidene Isomers of Titanium. DFT Analysis of the C-F Bond Activation Pathway and Rotation of the Titanium Alkylidene Moiety. Andino, J. G.; Fan, H.; Fout, A. R.; Bailey, B. C.; Baik, M.-H.; Mindiola, D. J. J. Organomet. Chem. 2011, 696, 4138-4146.

Atom Economical Route to Substituted Pyridines via a Scandium Imide. Wicker, B. F.; Scott, J. L.; Fout, A. R.; Pink, M.; Mindiola, D. J. Organometallics 2011, 30, 2453-2456.

Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride [Fe33-N)]-. Powers, T. M.; Fout, A. R.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 3336-3338.

Synthetic and Mechanistic Studies of the Ring-opening and Denitrogenation of Pyridine and Picolines by a Ti-C Multiple Bond. Fout, A. R.; Buck, D. M.; Bailey, B. C.; Fan, H.; Huffman, J. C.; Baik, M.-H.; Mindiola, D. J. Organometallics 2010, 29, 5409-5422.

Dehydrofluorination of Fluorohydrocarbons by Titanium Alkylidynes via Sequential C-H/C-F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination. Fout, A. R.; Scott, J.; Miller, D. L.; Bailey, B. C.; Huffman, J. C.; Pink, M.; Mindiola, D. J. Organometallics 2009, 28, 331-347.

Lewis Acid Stabilized Methylidene and Oxoscandium Complexes. Scott, J.; Fan, H.; Wicker, B. F.; Fout, A. R.; Baik, M.-H.; Mindiola, D. J. J. Am. Chem. Soc. 2008, 130, 14438-14439.

A Transient V(III)-Alkylidene Complex: Oxidation Chemistry Including the Activation of N2 to Afford a Highly Porous Honeycomb-like Framework. Kilgore, U. J.; Sengelaub, C. A.; Pink, M.; Fout, A. R.; Mindiola, D. J. Angew. Chemie, Int. Ed. 2008, 47, 3769-3772.

Evidence for the Existence of a Terminal Imidoscandium Complex. Intermolecular C-H Activation and Trapping Reactions with the Transient Sc=NAr Linkage. Scott, J.; Basuli, F.; Fout, A. R.; Huffman, J. C.; Mindiola, D. J. Angew. Chemie. Int. Ed. 2008, 47, 8502-8505.

The Progression of Synthetic Strategies to Assemble Titanium Complexes Bearing the Terminal Imide Group. Fout, A. R.; Kilgore, U. J.; Mindiola, D. J. Chem. Eur. J. 2007, 13, 9428-9440.

Cyclic Denitrogenation of N-Heterocycles Applying a Homogenous Titanium Reagent. Fout, A. R.; Bailey, B. C.; Tomaszewski, J.; Mindiola, D. J. J. Am. Chem. Soc. 2007, 129, 12640-12641.

An Alkylidyne Analogue to Tebbe's Reagent. Trapping Reactions of a Titanium Neopentylidyne by Incomplete and Complete 1, 2-Additions. Bailey, B. C.; Fout, A. R.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. Angew. Chemie. 2007, 46, 8246-8249.

Snapshots of an Alkylidyne for Nitride Triple-Bond Metathesis.Bailey, B. C.; Fout, A. R.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Gary, J. B.; Johnson, M. J. A.; Mindiola, D. J. J. Am. Chem. Soc.2007, 129, 2234-2235.

A Co2N2 Diamond Core Resting State of Cobalt (I): A Three-Coordinate Co(I) Synthon Invoking an Unusual Pincer-Type Rearrangement. Fout, A. R.; Basuli, F.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Baik, M-H.; Mindiola, D. J. Angew. Chemie. 2006, 45, 3291-3295.

Titanium Complexes Supported by a Sterically Encumbering N-anchored Tris-arylphenoxide Ligand. Cortes, S. A.; Munoz Hernandez, M. A.; Nakai, H.; Castro-Rodriguez, I.; Meyer, K.; Fout, A. R.; Miller, D.L.; Huffman, J. C.; Mindiola, D. J. Inorg. Chem. Comm. 2005, 8, 903-907.

Manganese(I) Poly(mercaptoimidazolyl)borate Complexes: Spectroscopic and Structural Characterization of Mn···H-B Interactions in Solution and in the Solid State.Graham, L. A.; Fout, A. R.; Kuehne, K. R.; White, J. L.; Mookherji, B.; Marks, F. M.; Yap, G. P. A.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 1, 171-180.