Complete Publication List

[1980's] [1990's] [2000's] [2010's] [Patents and Other Publications]

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1. Girolami, G. S.; Andersen, R. A. "Preparation of Mo(t-BuNC)5X2 (X = O2CCF3,Cl) and Re(t-BuNC)5Cl by Cleavage of the Quadruple Bond in Mo2(O2CCF3)4, K4Mo2Cl8, and Re2(O2CMe)4Cl2," J. Organomet. Chem. 1979, 182, C43 Link to pdf.

2. Girolami, G. S.; Mainz, V. V.; Andersen, R. A. "Coordination Complexes of Tetrakis(trifluoroacetato)dimolybdenum. A Solution 1H, 19F, and 31P Nuclear Magnetic Resonance and Infrared Spectroscopic Study," Inorg. Chem. 1980, 19, 805. Link to pdf.

3. Girolami, G. S.; Andersen, R. A. "Reaction of Binuclear Carboxylate Complexes of Molybdenum, Rhenium, Ruthenium, and Rhodium with tert-Butyl Isocyanide: Metal-Metal Bond Cleavage vs. Bond Retention," Inorg. Chem. 1981, 20, 2040. Link to pdf.

4. Girolami, G. S.; Mainz, V. V.; Andersen, R. A.; Vollmer, S. H.; Day, V. W. "Quadruply Bonded Tetramethyltetrakis(trialkylphosphine) dimolybdenum Compounds: Phosphine Exchange Kinetics, Acetone Formation with Carbon Monoxide, and Crystal Structure of Mo2Me4(PMe3)4," J. Am. Chem. Soc. 1981, 103, 3953. Link to pdf.

5. Girolami, G. S.; Andersen, R. A. "Crystal Structure of the Axial (Orange-Yellow) Isomer of Bis(methyldiphenylphosphine)tetrakis (trifluoroacetato)dimolybdenum," Inorg. Chem. 1982, 21, 1318. Link to pdf.

6. Girolami, G. S.; Mainz, V. V.; Andersen, R. A. "Quadruply Bonded Dimolybdenum Compounds of the Type Mo2(O2CR)2X2(PR3)2: Evidence for Kinetic and Structural Trans Effects," J. Am. Chem. Soc. 1982, 104, 2041. Link to pdf.

7. Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse,M. B. "Tertiary Phosphine Adducts of Manganese(II) Dialkyls. Part 2. Synthesis, Properties, and Structures of Monomeric Complexes," J. Chem. Soc., Dalton Trans. 1983, 2631. Link to pdf.

8. Girolami, G. S.; Salt, J. E.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "Alkyl, Hydride, and Dinitrogen 1,2-Bis(dimethylphosphino) ethane Complexes of Chromium. Preparation and Crystal Structures of Cr(CH3)2(dmpe)2, CrH4(dmpe)2,and Cr(N2)2(dmpe)2," J. Am. Chem. Soc. 1983, 105, 5954. Link to pdf.

9. Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "Hydrido, Alkyl, and Ethylene 1,2-Bis(dimethylphosphino)ethane Complexes of Manganese and the Crystal Structures of MnBr2(dmpe)2, [Mn(AlH4)(dmpe)2]2, and MnMe2(dmpe)2," J. Am. Chem. Soc. 1983, 105, 6752. Link to pdf.

10. Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "Manganese(IV) Alkyl Complexes. Synthesis and Structure of Tetramethyl[1,2-bis(dimethylphosphino)ethane]manganese(IV)," J. Chem. Soc., Chem. Commun.1983, 1163. Link to pdf.

11. Howard C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "Tertiary Phosphine Adducts of Manganese(II) Dicyclopentadienide. Magnetic Studies and Structural Characterization of 'Tilted' Cyclopentadienyl Rings," J. Am. Chem. Soc. 1984, 105, 2033 Link to pdf.

12. Behling, T.; Girolami, G. S.; Wilkinson, G.; Somerville, R. G.; Hursthouse, M. B. "Alkyl and Hydrido Derivatives of Tetrakis(trimethylphosphine)osmium(II). X-ray Crystal Structure of the Metallacycle Os[(CH2)2SiMe2](PMe3)4," J. Chem. Soc., Dalton Trans. 1984, 877. Link to pdf.

13. Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "η5-Cyclopentadienyl and η5-Methylcyclopentadienyl 1,2-Bis(dimethylphosphino)ethane Complexes of Titanium(II). The Crystal Structure of Ti(C5H4Me)2(dmpe)," J. Chem. Soc., Dalton Trans. 1984, 2347. Link to pdf.

14. Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. "1,2-Bis(dimethylphosphino)ethane (dmpe) Alkyl Compounds of Zirconium (IV) and Hafnium(IV). Crystal Structures of Zr(CH3)4(dmpe)2 and Zr(CH2Ph)4(dmpe)," J. Chem. Soc., Dalton Trans. 1984, 2789. Link to pdf.

15. Salt, J. E.; Girolami, G. S.; Wilkinson, G.; Motevalli, M.; Thornton-Pett, M.; Hursthouse, M. B. "Synthesis and Characterization of 1,2- Bis(dimethylphosphino)ethane(dmpe) Complexes of Chromium-(0) and -(IV). X-ray Crystal Structures of trans-Cr(N2)2(dmpe)2, cis-Cr(CO)2(dmpe)2, Cr(C2Ph2)2(dmpe), and CrH4(dmpe)2," J. Chem. Soc., Dalton Trans. 1985, 685. Link to pdf.

16. Girolami, G. S.; Howard, C. G.; Wilkinson, G.; Dawes, H. M.; Thornton-Pett, M.; Motevalli, M.; Hursthouse, M. B. "Alkyl, Hydrido, and Tetrahydroaluminato Complexes of Manganese with 1,2-Bis(dimethylphosphino)ethane (dmpe). X-ray Crystal Structures of Mn2(μ-C6H11)2(C6H11)2(μ-dmpe), (dmpe)2Mn(μ-H)2AlH(μ-H)2AlH(μ-H)2Mn(dmpe)2, and Li4{MnH(C2H4)[CH2(Me)PCH2CH2PMe2]}2•2Et2O," J. Chem. Soc., Dalton Trans. 1985, 921. Link to pdf.

17. Girolami, G. S.; Wilkinson, G.; Galas, A. M. R.; Thornton-Pett, M.; Hursthouse, M. B. "Synthesis and Properties of the Divalent 1,2-Bis(dimethylphosphino)ethane (dmpe) Complexes MCl2(dmpe)2 and MMe2(dmpe)2 (M = Ti, V, Cr, Mn, or Fe). X-ray Crystal Structures of MCl2(dmpe)2 (M =Ti, V, or Cr), MnBr2(dmpe)2, TiMe1.3Cl0.7(dmpe)2, and CrMe2(dmpe)2," J. Chem. Soc., Dalton Trans. 1985, 1339. Link to pdf.

18. Jensen, J. A.; Girolami, G. S. "Transition Metal Tetrahydridoborates as Models of Methane Activation: Synthesis and Structure of Ti(BH4)3(PMe3)2," J. Chem. Soc., Chem. Commun. 1986, 1160. Link to pdf.

19. Girolami, G. S.; Milam, S. N.; Suslick, K. S. "Synthesis and Characterization of Actinide Mono- and Bis(porphyrin) Complexes," Inorg. Chem. 1987, 26, 343. Link to pdf.

20. Girolami, G. S.; Jensen, J. A.; Pollina, D. M.; Williams, W. S.; Kaloyeros, A. E.; Allocca, C. M. "Organometallic Route to the Chemical Vapor Deposition of Titanium Carbide Films at Exceptionally Low Temperatures,"J. Am. Chem. Soc. 1987, 109, 1579. Link to pdf.

21. Hermes, A. R.; Girolami, G. S. "Fourteen-Electron Organoiron Species: Synthesis and Characterization of High-Spin Iron(II) Alkyls and the Crystal Structure of the Benzyl Derivative Fe(CH2C6H4CH3)2(dippe)," Organometallics 1987, 6, 763. Link to pdf.

22. Kaloyeros, A. E.; Williams, W. S.; Allocca, C. M.; Pollina, D. M.; Girolami, G. S. "Amorphous Titanium Carbide Films Produced by Low- Temperature Organometallic CVD," Adv. Ceram. Mater. 1987, 2, 257. Link to pdf.

23. Morris, R. J.; Girolami, G. S. "Isolation and Characterization of the First face="Symbol" s-Organomanganese(III) Complex. Crystal and Molecular Structure of (2,4,6-Trimethylphenyl)dibromobis(trimethylphosphine)manganese(III)," Organometallics 1987, 6, 1815. Link to pdf.

24. Gardner, T. G.; Girolami, G. S. "Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis and X-ray Crystal Structures of [t-BuSi (CH2PMe2)3]Ti(CO)4 and [t-BuSi(CH2PMe2)3]V(CO) 3H," Organometallics 1987, 6, 2551. Link to pdf.

25. Jensen, J. A.; Wilson, S. R.; Schultz, A. J.; Girolami, G. S. "Divalent Titanium Chemistry. Synthesis, Reactivity, and X-ray and Neutron Diffraction Studies of Ti(BH4)2(dmpe)2 and Ti(CH3)2(dmpe)2," J. Am. Chem. Soc. 1987, 109, 8094. Link to pdf.

26. Gardner, T. G.; Girolami, G. S. "The First Tris(n-butyl)Transition Metal Complex. Synthesis and Structures of the Fifteen Electron Chromium (III) Alkyls [ButSi(CH2PMe2)3]CrMe3 and [ButSi(CH2PMe 2)3]CrBun3," J.Chem. Soc. Chem. Commun. 1987, 1758. Link to pdf.

27. Hermes, A. R.; Girolami, G. S. "Unidentate vs. Bidentate Acyl Coordination: Reactions of High-Spin Iron(II) Alkyls with Carbon Monoxide and the Crystal Structure of the Bidentate Acyl Fe(η2-COC 6H 2Me3) Br(CO)(dippe)," Organometallics 1988, 7, 394. Link to pdf.

28. Dempsey, D. F.; Girolami, G. S. "Copper(I) Alkyls. Synthesis and Characterization of Tertiary Phosphine Adducts and the Crystal Structure of the Dimethylcuprate Complex [Cu(PMe3)4][CuMe2]," Organometallics 1988, 7, 1208. Link to pdf.

29. Jensen, J. A.; Gozum, J. E.; Pollina, D. M.; Girolami, G. S. "Titanium, Zirconium, and Hafnium Tetrahydroborates as 'Tailored' CVD Precursors for Metal Diboride Thin Films," J. Am. Chem. Soc. 1988, 110, 1643. Link to pdf.

30. Jensen, J. A.; Wilson, S. R.; Girolami, G. S. "Titanium(III) Tetrahydroborates. Preparation and Crystal Structure of Ti(BH 4)3(PMe3)2 Containing an Unusual Ti•••H•••B Agostic Interaction," J. Am. Chem. Soc. 1988, 110, 4977. Link to pdf.

31. Girolami, G. S.; Milam, S. N.; Suslick, K. S. "Actinide Bis(porphyrinate) π-Radical Cations and Dications, Including the X-ray Crystal Structure of [(TPP)2Th][SbCl6]," J. Am. Chem. Soc. 1988, 110, 2011. Link to pdf.

32. Hermes, A. R.; Girolami, G. S. "Synthesis and Characterization of Coordinately Unsaturated Phosphine Complexes of Divalent V, Cr, Mn, Fe, and Co; Crystal Structures of [CrCl2(dippe)]2 and FeCl2(dippe)," Inorg. Chem. 1988, 27, 1775. Link to pdf.

33. Gozum, J. E.; Jensen, J. A.; Pollina, D. M.; Girolami, G. S. 'Tailored' Organometallics as Precursors for the Chemical Vapor Deposition of High-Purity Palladium and Platinum Thin Films," J. Am. Chem. Soc. 1988, 110, 2688. Link to pdf.

34. Hermes, A. R.; Morris, R. J.; Girolami, G. S. "Twelve-Electron Organochromium Species: Synthesis and Characterization of High-Spin Square-Planar Chromium(II) Alkyls and Aryls," Organometallics 1988, 7, 2372. Link to pdf.

35. Jensen, J. A.; Girolami, G. S. "Vanadium Tetrahydroborates: Preparation and Characterization of V(η2 -BH4)3(PMe3)2 and the Unusual Unidentate BH4- Complex V(η1-BH4)2(dmpe)2," J. Am. Chem. Soc. 1988, 110, 4450. Link to pdf.

36. Girolami, G. S.; Jensen, J. A.; Gozum, J. E.; Pollina, D. M. "Tailored Organometallics as Low-Temperature CVD Precursors to Thin Films," Mat. Res. Soc. Symp. Proc. 1988, 121, 429..

37. Gardner, T. G.; Girolami, G. S. "Titanium(0) Arene Complexes. Synthesis and X-ray Crystal Structure of (η6- C10H8)Ti[t-BuSi(CH2PMe2)3]," Angew. Chem., Int. Ed. Engl. 1988, 12, 1693. Link to pdf.

38. Morris, R. J.; Girolami, G. S. "A Square-Planar Oxo-Alkyl of Manganese(III). Synthesis and X-ray Crystal Structure of {Li2 [MnOMe3]•2Li2(Meacac)•tmed}2," Polyhedron 1988,7, 2001. Link to pdf.

39. Morris, R. J.; Girolami, G. S. "Permethyl Manganates. Synthesis and Characterization of Divalent [MnMe42-], Trivalent [MnMe52-], and Tetravalent [MnMe62-]," J. Am. Chem. Soc. 1988, 110, 6245. Link to pdf.

40. Jensen, J. A.; Girolami, G. S. "Synthesis, Characterization, and X-ray Crystal Structures of the Divalent Titanium Complex Ti( η2-BH4)2(dmpe)2 and the Unidentate Tetrahydroborate Complex V(η1-BH 4)2(dmpe)2," Inorg. Chem. 1989, 28, 2107. Link to pdf.

41. Jeffries, P. M.; Girolami, G. S. "Chemical Vapor Deposition of Copper and Copper Oxide Thin Films from Copper(I) tert-Butoxide," Chem. Mater. 1989, 1, 8. Link to pdf.

42. Jensen, J. A.; Girolami, G. S. "Vanadium(III) Tetrahydroborates. Preparation, Reaction Chemistry, and Crystal Structures of V (BH4)3(PMe3)2 and the Oxo Dimer [V(BH4)2(PMe3)\ 2]2O," Inorg. Chem. 1989, 28, 2114. Link to pdf.

43. Morris, R. J.; Girolami, G. S. "Thirteen-Electron Manganese(II) Tetraalkyls. Synthesis, Characterization, and X-ray Crystal Structures of [Li(tmed)]2[MnMe4] and the 'β-Unstable' Species [Li(tmed)]2[MnEt4] and [Li(tmed)] 2[Mn(CH2CH2-t-Bu)4]," Organometallics 1989, 8, 1478. Link to pdf.

44. Morse, P. M.; Girolami, G. S. "Are d0 ML6 Complexes Always Octahedral? The X-ray Structure of Trigonal Prismatic [Li(tmed)]2[ZrMe6],"J. Am. Chem. Soc. 1989, 111, 4114. Link to pdf.

45. Hermes, A. R.; Girolami, G. S. "Phosphine Complexes of Trivalent Early Transition Metals. X-ray Crystal Structure of the d1-d1 Dimer [TiCl3(dippe)]2 and Synthesis of the Alkyl CrMeCl2(dippe)(thf)," Inorg. Chem. 1990, 29, 313. Link to pdf.

46. Morse, P. M.; Wilson, S. R.; Girolami, G. S. "A Compound with a Hf-Hf Bond. The First Structurally Characterized Hafnium(III) Complex: Hf2Cl6[(i-Pr)2PCH2CH2P(i-Pr)2]2," Inorg. Chem. 1990, 29, 3200. Link to pdf.

47. Bilsel, O.; Rodriguez, J.; Holten, D.; Girolami, G. S.; Milam, S. N.; Suslick, K. S. "Observation of a New Low-Energy Fluorescent 1ππ*) Excited State in Strongly-Coupled Porphyrin Dimers," J. Am. Chem. Soc. 1990, 112, 4075. Link to pdf.

48. Girolami, G. S.; Gozum, J. E. "Low Temperature MOCVD Routes to Thin Films from Transition Metal Precursors," Mat. Res. Soc. Symp. Proc. 1990, 168, 319. Link to pdf

49. Morris, R. J.; Girolami, G. S. "On the π-Donor Ability of Early Transition Metals: Evidence that Trialkylphosphines Can Engage in π-Back-Bonding and X-ray Structure of the Titanium(II) Phenoxide Ti(OPh)2(dmpe)2,"Inorg. Chem. 1990, 29, 4167. Link to pdf.

50. Rogers, D. M.; Wilson, S. R.; Girolami, G. S. "Bis(cyclooctatetraenyl)zirconium: X-ray Crystal Structure and Solution and Solid State NMR Spectra," Organometallics 1991, 10, 2419. Link to pdf.

51. Gozum, J. E.; Girolami, G. S. "Zirconium and Hafnium Polyhydrides. Preparation and Characterization of M2H3 (BH4)5(PMe3)2, MH(BH4)3(dmpe), and MH2(BH4) 2(dmpe)2," J. Am. Chem. Soc. 1991, 113, 3829. Link to pdf.

52. Morris, R. J.; Girolami, G. S. "High-Valent Organomanganese Chemistry. 1. Synthesis and Characterization of MnIII and MnIV Alkyls," Organometallics 1991, 10, 792. Link to pdf.

53. Morris, R. J.; Girolami, G. S. "High-Valent Organomanganese Chemistry. 2. Synthesis and Characterization of MnIII Aryls," Organometallics 1991, 10, 799. Link to pdf.

54. Kim, K.; Lee, W. S.; Kim, H.-J.; Cho, S.-H.; Girolami, G. S.; Gorlin, P. A.; Suslick, K. S. "Synthesis and Structure of Transition Metal Bis(porphyrinato) Complexes. Characterization of Zr(TPP)2 and Zr(OEP)2," J. Am. Chem. Soc. 1991, 30, 2652. Link to pdf.

55. Girolami, G. S.; Riehl, M. E.; Suslick, K. S.; Wilson, S. R. "A Rare Example of a Monomeric Aryllithium Complex. X-ray Crystal Structure of (2,4,6-Triphenylphenyl)lithium Bis(diethyl ether)," Organometallics 1992, 11, 3907. Link to pdf.

56. Dubois, L. H.; Jeffries, P. M.; Girolami, G. S. "The Growth of Copper Thin Films from Volatile Cu(I) and Cu(II) Precursors," in Advanced Metallization for ULSI Applications; Rana, V. S.; Joshi, R. V.; Ohdomari, I. eds; Materials Research Society: Pittsburgh 1992, p 375.

57. Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. "Electronic States and Optical Properties of Porphyrins in van der Waals Contact: ThIV Sandwich Complexes," J. Am. Chem. Soc. 1992, 114, 6528. Link to pdf.

58. Jeffries, P. M.; Dubois, L. H.; Girolami, G. S. "Metal-Organic Chemical Vapor Deposition of Copper and Copper(I) Oxide from Copper(I) tert-Butoxide," Chem. Mater. 1992, 4, 1169. Link to pdf.

59. Jeffries, P. M.; Wilson, S. R.; Girolami, G. S. "Synthesis and Characterization of Monomeric Copper(II) Fluoroalkoxides," Inorg. Chem. 1992, 31, 4503. Link to pdf.

60. Gozum, J. E.; Wilson, S. R.; Girolami, G. S. "Zirconium and Hafnium Polyhydrides. 2. Preparation and Characterization of M 3H 6(BH4)6(PMe3)4 and M2H4(BH4) 4(dmpe)2," J. Am. Chem. Soc. 1992, 114, 9483. Link to pdf.

61. Dubois, L. H.; Zegarski, B. R.; Girolami, G. S. "Infrared Studies of the Surface and Gas Phase Reactions Leading to the Growth of Titanium Nitride Thin Films from Tetrakis(dimethylamido)titanium and Ammonia," J. Electrochem. Soc. 1992, 139, 3603. Link to pdf.

62. Girolami, G. S.; Gladfelter, W. L. "Conference Report: Molecular Routes to Materials in New York," Adv. Mater. 1992, 4, 443 Link to pdf.

63. Girolami, G. S.; Jeffries, P. M.; Dubois, L. H., "Mechanistic Studies of Copper Thin Film Growth from CuI and CuII face β- Diketonates," J. Am. Chem. Soc. 1993, 115, 1015. Link to pdf.

64. Jeffries, P. M.; Wilson, S. R.; Girolami, G. S. "Crystal Structure of [CF3CF=C(CF3)Ag]4 and Its Use as a Chemical Vapor Deposition Prescursor for Silver Films," J. Organomet. Chem. 1993, 449, 203. Link to pdf.

65. Riehl, M. E.; Wilson, S. R.; Girolami, G. S. "Synthesis, X-ray Crystal Structure, and Phosphine Exchange Reactions of the Hafnium (III)-Hafnium(III) Dimer Hf2Cl6(PEt3)4," Inorg. Chem. 1993, 32, 218. Link to pdf.

66. Spencer, M. D.; Morse, P. M.; Wilson, S. R.; Girolami, G. S. "Preparation, Catalytic Reactivity, and X-ray Crystal Structure of the First Group 4 Alkyl/Alkene Complexes. The First Structural Models of the Key Ziegler-Natta Intermediate," J. Am. Chem. Soc. 1993, 115, 2057. Link to pdf.

67. Lin, W.; Wilson, S. R.; Girolami, G. S. "Reversible C-Si Bond Cleavage in the Methylene/Silyl Complex Cp*2Ru2 μ-CH2)μ-Cl)(SiMe3)," J. Am. Chem. Soc. 1993, 115, 3022. Link to pdf.

68. Lin, W.; Wilson, S. R.; Girolami, G. S. "The First Unsubstituted Metallabenzene Complex [Ru2η5- C5Me5)2η25-C5H5)(SiMe3)]," J. Chem. Soc., Chem. Commun. 1993, 284. Link to pdf.

69. Hostetler, M. J.; Dubois, L. H.; Nuzzo, R. H.; Girolami, G. S. "Ring Contraction of 1,3-Cyclooctadiene, 1,5-Cyclooctadiene, and Cyclooctatetraene to Benzene on Platinum(111) Surfaces," J. Am. Chem. Soc. 1993, 115, 2044. Link to pdf.

70. Bilsel, O.; Milam, S. N.; Girolami, G. S.; Suslick, K. S.; Holten, D. "Ultrafast Electronic Deactivation and Vibrational Dynamics of Photoexcited Uranium(IV) Porphyrin Sandwich Complexes," J. Phys. Chem. 1993, 97, 7216. Link to pdf.

71. Lin, W.; Warren, T. H.; Nuzzo, R. G.; Girolami, G. S. "Surface-Selective Deposition of Palladium and Silver Films from Metal-Organic Precursors: A Novel MOCVD Redox Transmetallation Process," J. Am. Chem. Soc. 1993, 115, 11644. Link to pdf.

72. Girolami, G. S. "A Simple 'Back of the Envelope' Method for Estimating the Densities and Molecular Volumes of Liquids and Solids," J. Chem. Educ. 1994, 71, 962. Link to pdf.

73. Morris, R. J.; Wilson, S. R.; Girolami, G. S. "Vanadium(II) Alkyls. Synthesis and X-ray Crystal Structures of trans-VMe2 (dmpe)2 and cis-V(CH2SiMe3)2(dmpe)2," J. Organomet. Chem. 1994, 480, 1. Link to pdf.

74. Girolami, G. S.; Gorlin, P. A.; Suslick, K. S. "Electronically Asymmetric Bis(porphyrin) Sandwich Complexes," Inorg. Chem. 1994, 33, 626. Link to pdf.

75. Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S.; Dubois, L. H. "Structure-Reactivity Correlations in the Reactions of Hydrocarbons on Transition Metal Surfaces. 1. Ring Contraction of Cyclooctene, 1,3-Cyclooctadiene, 1,5-Cyclooctadiene and Cyclooctatetraene to Benzene on a Platinum(111) Surface," J. Phys. Chem. 1994, 98, 2952. Link to pdf.

76. Lin, W.; Wilson, S. R.; Girolami, G. S. "Synthesis and X-ray Crystal Structure of a New Palladium(I) Dimer [Pd 2 (PMe3)6][hfac]2 and its Conversion to [PdMe(PMe3)3] [hfac] via Activation of Phosphorus-Carbon Bonds," Inorg. Chem. 1994, 33,2265. Link to pdf.

77. Girolami, G. S.; Gorlin, P. A.; Milam, S. N.; Suslick, K. S.; Wilson, S. R. "Bis(porphyrin)actinide Complexes and their Radical Cations and Dications," J. Coord. Chem. 1994, 32, 173. Link to pdf.

78. Entley, W. R.; Girolami, G. S. "New Three-DimensionalFerrimagnetic Materials:K2Mn[Mn(CN)6],Mn3 [Mn(CN)6]212H2O, and CsMn[Mn(CN)6]1/2H2O," Inorg. Chem. 1994, 33, 5165. Link to pdf.

79. Morse, P. M.; Spencer, M. D.; Wilson, S. R.; Girolami, G. S. "AStatic α-CH•••MInteraction Observable by NMR Spectroscopy: Synthesis of the Chromium(II) Alkyl [Cr2(CH2SiMe3)62-] and its Conversion to the Unusual 'Windowpane' Bis(metallacycle) Complex [Cr(κ2CC-CH2SiMe 2CH2)22-]," Organometallics 1994, 13, 1646. Link to pdf.

80. Lin, W.; Wilson, S. R.; Girolami, G. S. "A Reversible Silicon-Carbon Bond Cleavage Process. Dynamics and Reactivity of Cp*2 Ru2(μ-CH2)(SiMe3)(μ-Cl)," Organometallics 1994, 13, 2309. Link to pdf.

81. Spencer, M. D.; Girolami, G. S. "Synthesis and Characterization of New Titanium(II) Carbonyls of Stoichiometry TiX2(CO) 2(dmpe)2: An NMR Study," J. Organomet. Chem. 1994, 483, 99. Link to pdf.

82. Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S. "Reactions of Primary Silanes on Transition Metal Surfaces. Identification of the First Surface-Bound Organosilylynes," J. Am. Chem. Soc. 1994, 116, 11608. Link to pdf.

83. Cheon, J.; Dubois, L. H.; Girolami, G. S. "Chemical Vapor Deposition of Zinc from Diallyl Zinc Precursors," Chem. Mater. 1994, 6, 2279. Link to pdf.

84. Gross, C. L.; Wilson, S. R.; Girolami, G. S. "Synthesis and Characterization of (C5Me5) 2Os2Br2and the Osmium Polyhydride (C5Me5)OsH5: A New Synthetic Entry into Mono(pentamethylcyclopentadienyl)osmium Chemistry," J. Am. Chem. Soc. 1994, 116, 10294. Link to pdf.

85. You, Y; Wilson, S. R.; Girolami, G. S. "Synthesis and Catalytic Activity of Mono(cyclopentadienyl)titanium(II) Complexes: X-ray Crystal Structures of CpTi(Me2PCH2CH2PMe2)2X and Cp*Ti(η2 -BH4)[η2-(Me2PCH2)3Si(t-Bu)]," Organometallics 1994, 13, 4655. Link to pdf.

86. Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S. "Structure-Reactivity Correlations in the Reactions of Hydrocarbons on Transition Metal Surfaces. 2. Hydrogenation of Norbornene and Bicyclo[2.2.2]octene on Platinum(111) Surfaces," J. Am. Chem. Soc. 1995, 117, 1814. Link to pdf.

87. Girolami, G. S.; Morris, R. J. "High Valent Organomanganese Compounds," In Comprehensive Organometallic Chemistry II, Abel, E. W.; Stone, F. G. A.; Wilkinson, G., Eds., Pergamon Press, Oxford, 1995, Volume 6, Chapter 7.

88. Gross, C. L.; Wilson, S. R.; Girolami, G. S. "Synthesis and Characterization of [(C5Me5 2OsH]2[Os2Br8]. The Eclipsed Rotamer of the Triply-Bonded Os 2Br82-Anion," Inorg. Chem. 1995, 34, 2582. Link to pdf.

89. Hermes, A. R.; Warren, T. H.; Girolami, G. S. "Iron(0) Arene and Iron(II) Hydride Complexes from the Hydrogenation and Thermolysis of High-Spin Iron(II) Alkyls," J. Chem. Soc., Dalton Trans. 1995, 301. Link to pdf.

90. Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S.; Dubois, L. H. "Norbornadiene on Pt(111) is Not Bound as an η2, η2 Diene: Characterization of an Unexpected η2η1 Bonding Mode Involving an Agostic Pt•••H-C Interaction," Organometallics 1995, 14, 3377. Link to pdf.

91. Entley, W. R.; Girolami, G. S. "New High-Temperature Molecular Magnets Based on Cyanovanadate Building Blocks: Spontaneous Magnetization at 230 K," Science 1995, 268, 397. Link to pdf.

92. Entley, W. R.; Treadway, C. R.; Girolami, G. S. "Molecular Magnets Constructed from Cyanometalate Building Blocks," Mol. Cryst. Liq. Cryst. 1995, 273, 153. Link to pdf.

93. Hostetler, M. J.; Manner, W. L.; Nuzzo, R. G.; Girolami, G. S. "Two-Dimensional Melting Transitions of Rod-like Molecules Analyzed by Reflection-Absorption Infrared Spectroscopy," J. Phys. Chem. 1995, 99, 15269. Link to pdf.

94. Lin, W.; Wiegand, B. C.; Nuzzo, R. G.; Girolami, G. S. "Mechanistic Studies of Palladium Thin Film Growth from Palladium(II) β-Diketonates. 1. Spectroscopic Studies of the Reactions of Bis(hexafluoroacetylacetonato)palladium(II) on Copper Surfaces," J. Am. Chem. Soc. 1996, 118, 5977. Link to pdf.

95. Lin, W.; Nuzzo, R. G.; Girolami, G. S. "Mechanistic Studies of Palladium Thin Film Growth from Palladium(II) β-Diketonates. 2. Kinetic Analysis of the Transmetalation Reaction of Bis(hexafluoroacetylacetonato)palladium(II) on Copper Surfaces," J. Am. Chem. Soc. 1996, 118, 5988. Link to pdf.

96. Tagge, C. D.; Simpson, R. D.; Bergman, R. G.; Hostetler, M. J.; Girolami, G. S.; Nuzzo, R. G. "Synthesis and Structure of a Novel Volatile Platinum Complex for Use in CVD and a Study of the Mechanism of its Thermal Decomposition in Solution," J. Am. Chem. Soc. 1996, 118, 2634. Link to pdf.

97. Girolami, G. S.; Hein, C. L.; Suslick, K. S. "A Zirconium Bis(porphyrinate) Sandwich Complex with an Appended Quinone," Angew. Chem., Int. Ed. Engl. 1996, 35, 1223. Link to pdf.

98. Gross, C. L.; Girolami, G. S. "Synthesis and Characterization of Osmium(II) Compounds of Stoichiometry (C5Me5) OsL2Br, (C5Me5)OsL2H, and (C5Me5)Os(NO)Br2," Organometallics 1996, 15, 5359. Link to pdf.

99. Spencer, M. D.; Wilson, S. R.; Girolami, G. S. "Butadiene Complexes of Titanium(II) and Titanium(0): Synthesis, Butadiene Dimerization Catalysis, and Crystal Structures of TiMe24-1,4-C4H4Ph2)(dmpe) and Ti(η 4-C4H6)2(dmpe)," Organometallics 1997, 16, 3055. Link to pdf.

100. Entley, W. R.; Treadway, C. R.; Wilson, S. R.; Girolami, G. S. "The Hexacyanotitanate Ion: Synthesis and Crystal Structure of [NEt 4]3[Ti(CN)6]•4MeCN," J. Am. Chem. Soc. 1997, 119, 6251. Link to pdf.

101. Lin, W.; Wilson, S. R.; Girolami, G. S. "Synthesis and Reactivity of Dinuclear Platinum Complexes. NMR Spectra of [Pt2 (PMe3)6][hfac]2and an Unusual β-Diketonate Bridging Mode in [Pt2(μ,η2, η2-hfac)(PMe3)4][hfac]," Inorg. Chem. 1997, 36, 2262. Link to pdf.

102. Holmes, S. M.; Girolami, G. S. "New Prussian Blue Analogues Constructed from the [Cr(CN)5NO3-] and [Cr(CN)64-] Anions. A Building Block Approach to High TNFerrimagnets," Mol. Cryst. Liq. Cryst. 1997, 305, 279. Link to pdf.

103. Lin, W; Wilson, S. R.; Girolami, G. S. "Synthesis and Reactivity of New Ruthenium Alkyls and Hydrides. Protonation of Cp*Ru(Me2PCH2PMe2)Me and X-ray Crystal Structure of Cp*2Ru2(μ-Ph 2PCH2PPh2)(AlH5)," Organometallics 1997, 16, 2987. Link to pdf.

104. Lin, W.; Wilson, S. R.; Girolami, G. S. "Carbon-Carbon Bond Formation Promoted by Organoruthenium Complexes. The First Unsubstituted π-Metallabenzene Complex Cp*2Ru22η5-C5H5)(SiMe 3) and Synthesis of the Tetramethyleneethane Complex Cp*2Ru23η 3-C6H8)Cl4," Organometallics 1997, 16, 2356. Link to pdf.

105. Cheon, J.; Gozum, J. E.; Girolami, G. S. "Chemical Vapor Deposition of MoS2 and TiS2 Films from the Metal-Organic Precursors Mo(S-t-Bu)4 and Ti(S-t-Bu)4," Chem. Mater. 1997, 9, 1847. Link to pdf.

106. Cheon, J.; Rogers, D. M.; Girolami, G. S. "Mechanistic Studies of the Thermolysis of Tetra(neopentyl)titanium(IV). 1. Solution Evidence that Titanium Alkylidenes Activate Saturated Hydrocarbons," J. Am. Chem. Soc. 1997, 119, 6804. Link to pdf.

107. Cheon, J.; Dubois, L. H.; Girolami, G. S. "Mechanistic Studies of the Thermolysis of Tetra(neopentyl)titanium(IV). 2. Solid State and High Vacuum Studies of the Chemical Vapor Deposition of TiC Films," J. Am. Chem. Soc. 1997, 119, 6814. Link to pdf.

108. Jeon, N. L.; Lin, W.; Erhardt, M. K.; Girolami, G. S.; Nuzzo, R. G. "Selective Chemical Vapor Deposition of Platinum and Palladium Directed by Monolayers Patterned Using Microcontact-Printing," Langmuir 1997, 13, 3833. Link to pdf.

109. Jeon, N. L.; Clem. P.; Jung. D. Y.; Lin, W.; Girolami, G. S.; Payne, D. A.; Nuzzo, R. G. "Additive Fabrication of Integrated Ferroelectric Thin Film Capacitors Using Self-Assembled Organic Thin-Film Templates," Adv. Mater. 1997, 9, 891. Link to pdf.

110. Gross, C. L.; Schultz, A. J.; Girolami, G. S. "Neutron Diffraction Study of the 'Elongated' Molecular Dihydrogen Complex [Cp*Os(H2)H2(PPh3)+]," J. Chem. Soc., Dalton Trans. 1997, 3081. Link to pdf.

110a. Jeon, N. L.; Clem, P.; Jung, D. Y.; Lin, W.; Finnie, K.; Erhardt, M.; Girolami, G. S.; Payne, D. A.; Nuzzo, R. G. "Additive Fabrication of Integrated Multilevel Thin Film Microstructures using Printed Thin-Film Templates," Poly. Mater. Sci. Eng. 1997, 77, 398. Link to pdf.

111. Hermes, A. R.; Girolami, G. S. "An Active Form of Titanium(III) Chloride," Inorg. Synth. 1998, 32, 309. Link to pdf.

112. Bishop, A. R.; Hostetler, M. J.; Girolami, G. S.; Nuzzo, R. G. "Transport Dynamics in Ordered Bilayer Assemblies of the n-Alkanes on Pt(111)," J. Am. Chem. Soc. 1998, 120, 3305. Link to pdf.

113. Gross, C. L.; Girolami, G. S. "Metal-Alkane Complexes. Rapid Exchange of Hydrogen Atoms between Hydride and Methyl Ligands in [(C5Me5)Os(dmpm)(CH3)H+]," J. Am. Chem. Soc. 1998, 120, 6605. Link to pdf.

114. Manner, W. L.; Girolami, G. S.; Nuzzo, R. G. "Sequential Dehydrogenation of Cyclic C5 and C6 Hydrocarbons on Pt(111)," J. Phys. Chem. B 1998, 102, 10295. Link to pdf.

115. Manner, W. L.; Dubois, L. H.; Girolami, G. S.; Nuzzo, R. G. "Carbon-Hydrogen Bond Activation and Cyclodehydrogenation Reactions of Cyclic C8 Hydrocarbons on Pt(111)," J. Phys. Chem. B 1998, 102, 2391. Link to pdf.

116. Manner, W. L.; Girolami, G. S.; Nuzzo, R. G. "The C-H•••M Interaction and Reactivity Differences of n-Octane on the (1X1) and (5X20) Surfaces of Pt(100)," Langmuir 1998, 14, 1716. Link to pdf.

117. Manner, W. L.; Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. "Melting of Rodlike Molecules on Pt(111). Infrared Spectroscopic Studies of Isotopically Labeled n-Alkanes," J. Phys. Chem. B 1998, 102, 8816. Link to pdf.

118. Jefferis, J. M; Girolami, G. S. "Crystal Structure of '[Li(Et2O)]4[FePh4]': Corrigendum and Reformulation. A Remarkable Example of a False Solution in a Wrong Space Group," Organometallics 1998, 17, 3630. Link to pdf.

119. Awaga, K.; Sekine, T.; Okawa, M.; Fujita, W.; Holmes, S. M.; Girolami, G. S. "High-Pressure Effects on a Manganese Hexacyanomanganate Ferrimagnet with TN= 29 K," Chem. Phys. Lett. 1998, 293, 352. Link to pdf.

120. Manner, W. L.; Hostetler, M. J.; Girolami, G. S.; Nuzzo, R. G. "Structures and Reactivities of Cycloheptane, Cycloheptene, 1,3-Cycloheptadiene, and Cycloheptatriene on Pt(111)," J. Phys. Chem. B 1999, 103, 6752. Link to pdf.

121. Nelsen, M. J.; Girolami, G. S. "Synthesis and Characterization of Zirconium Pentafluorophenyl Complexes:  X-ray Crystal Structures of [ZrCl2(C6F5)42-] and [ZrF2(C 6F5) 3-]," J. Organomet. Chem. 1999, 585, 275. Link to pdf.

122. Shelby, Q. D.; Girolami. G. S. "Metal-to-Metal Silyl Migration and Silicon-Carbon Bond Cleavage/Reformation Processes in the Methylene/Silyl Complexes Cp*2Ru2(μ-CH2)(SiR3)(μ-Cl)," Organometallics 1999, 18, 1904. Link to pdf.

123. Brumaghim, J. L.; Girolami, G. S. "Ring-Opening Metathesis Polymerization of Norbornene by Cp*2 Os2Br4 and Related Compounds," Organometallics 1999, 18, 1923. Link to pdf.

124. Brumaghim, J. L.; Priepot, J. G.; Girolami, G. S. "Synthesis of Hydride and Alkyl Compounds Containing the Cp*Os(NO) Fragment. Crystal Structure of [Cp*Os(NO)]2," Organometallics 1999, 18, 2139. Link to pdf.

125. Holmes, S. M.; Girolami, G. S. "Sol-Gel Synthesis of KVII[CrIII(CN)6]•2H2 O: a Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 °C,"J. Am. Chem. Soc. 1999, 121, 5593. Link to pdf.

126. Brumaghim, J. L.; Girolami, G. S. "An Unusual Norbornadiene Coupling Product. Synthesis, Characterization, and Structure of the Ruthenocene Cp*Ru(η5-C5H4C9H11)," J. Organomet. Chem. 1999, 586, 258. Link to pdf.

127. Brumaghim, J. L.; Gross, C. L.; Girolami, G. S. "Synthesis and Reactivity of the Osmium Methylidene Complex [(C5Me5) Os(=CH2)(dppm)][OTf]," Chem. Commun. 1999, 953. Link to pdf.

128. Mui, H. D.; Brumaghim, J. L.; Gross, C. L.; Girolami, G. S. "Synthesis of Hydride and Alkyl Compounds Containing the Cp*Os (η 3-allyl) Fragment. Crystal Structures of Cp*Os(η3-C8H13)Br 2 and [Cp*Osη3-C4H7)Me(H2O)][BF4]," Organometallics 1999, 13, 3264. Link to pdf.

129. Shelby, Q. D.; Girolami, G. S. "Synthesis, Dynamic Behavior, and X-ray Crystal Structure of [Li(tmed)]3[WH(C2H 4)4]," Organometallics 1999, 18, 2297. Link to pdf

130. Jeon, N. L.; Choi, I. S.; Whitesides, G. M.; Kim, N. Y.; Laibinis, P. E.; Harada, Y.; Finnie, K. R.; Girolami, G. S.; Nuzzo, R. G. "Patterned Polymer Growth on Silicon Surfaces using Microcontact Printing and Surface-Initiated Polymerization," Appl. Phys. Lett. 1999, 75, 4201. Link to pdf.

131. Sung, J. H.; Goedde, D.; Girolami, G.S; Abelson, J. R. "Diffusion Barrier Characteristics of ZrB2 Films Grown by Remote Plasma CVD," Mater. Res. Soc. Symp. Proc. 1999, 563, 39. Link to pdf.

132. Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. "Structural Models and Thermal Desorption Energetics for Multilayer Assemblies of the n-Alkanes on Pt(111)," J. Phys. Chem. B. 2000, 104, 754. Link to pdf.

133. Bishop, A. R.; Girolami, G. S.; Nuzzo, R. G. "Surface-Mediated Segregation and Transport Processes in Mixed Hydrocarbon Multilayer Assemblies," J. Phys. Chem. B. 2000, 104, 747. Link to pdf.

134. Crane, E. L.; You, Y. J.; Nuzzo, R. G.; Girolami, G. S. "Mechanistic Studies of CVD Metallization Processes: Reactions of Rhodium and Platinum beta-Diketonate Complexes on Copper Surfaces," J. Am. Chem. Soc. 2000, 122, 3422. Link to pdf.

135. Kim, N. Y.; Jeon, N. L.; Choi, I. S.; Takami, S.; Harada, Y.; Finnie, K. R.; Girolami, G. S.; Nuzzo, R. G.; Whitesides, G. M.; Laibinis, P. E. "Surface-Initiated Ring-Opening Metathesis Polymerization on Si/SiO2 ," Macromolecules 2000, 33, 2793. Link to pdf.

136. Crane, E. L.; Girolami, G. S.; Nuzzo, R. G. "Additive Fabrication and the Mechanisms of Nucleation and Growth in Chemical Vapor Deposition Processes," Acc. Chem. Res. 2000, 33, 869. Link to pdf.

137. Holmes S. M.; McKinley, S. G.; Girolami, G. S. "Transition Metal p-Toluenesulfonates," Inorg. Synth. 2002, 33, 91. Link to pdf.

138. Sung, J. W.; Goedde, D. M.; Girolami, G. S.; Abelson, J. "Remote-Plasma Chemical Vapor Deposition of Conformal ZrB2 Films at Low Temperature: A Promising Diffusion Barrier for Ultralarge Scale Integrated Electronics," J. Appl. Phys. 2002, 91, 3904. Link to pdf.

139. Harada, Y.; Girolami, G. S.; Nuzzo, R. G. "Catalytic Amplification of Patterning via Surface-Confined Ring-Opening Metathesis Polymerization on Mixed Primer Layers Formed by Contact Printing." Langmuir 2003, 19, 510. Link to pdf.

140. Goedde, D. M.; Girolami, G. S. "A New Class of CVD Precursors to Metal Borides: Cr(B3H8)2 and Related Octahydratriborate Complexes,"J. Am. Chem. Soc. 2004, 126, 12230. Link to pdf.

141. Harada, Y.; Girolami, G. S.; Nuzzo, R. G. "Growth Kinetics and Morphology of Self-Assembled Monolayers Formed by Contact Printing 7-Octenyltrichlorosilane and Octadecyltrichlorosilane on Si(100) Wafers," Langmuir, 2004, 20, 10878-10888. Link to pdf.

142. Girolami, G. S. "Osmium," Chemistry: Foundations and Applications, Lagowski, J. J., Ed.; Macmillan: New York, 2004, vol 3, p. 208. Link to pdf.

143. Verdaguer, M.; Girolami, G. S. "Magnetic Prussian Blue Analogs," in Magnetism Molecules to Materials V, 2005, pp 283-346. Link to pdf.

144. Jayaramam, S.; Klein, E. J.; Yang, Y.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "Chromium Diboride Thin Films by Low Temperature Chemical Vapor Deposition," J. Vac. Sci. Technol. A 2005, 23, 631. Link to pdf.

145. Jayaraman, S.; Yang, Y.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "Hafnium Diboride Thin Films by Chemical Vapor Deposition from a Single Source Precursor," J. Vac. Sci. Technol. A. 2005, 23, 1619. Link to pdf.

146. Webster, C. E.; Gross, C. L.; Young, D. M.; Girolami, G. S.; Schultz, A. J.; Hall, M. B.; Eckert, J. "Electronic and Steric Effects on Molecular Dihydrogen Activation in [Cp*OsH4(L)]+ (L = PPh3, AsPh3, and PCy3)," J. Am. Chem. Soc. 2005, 127, 15091. Link to pdf.

147. Jayaraman,S.; Gerbi, J.E.; Yang, Y.; Kim, D. Y.; Chatterjee, A.; Bellon, P.; Girolami, G. S.; Chevalier, J.-P.; Abelson, J. R. "HfB2 and Hf-B-N Hard Coatings by Chemical Vapor Deposition," Surf. Coatings Technol. 2006, 200, 6629. Link to pdf.

148. Goedde, D. M.; Girolami, G. S. "Titanium(II) and Titanium(III) Tetrahydroborates. Crystal Structures of [Li(Et2O) 2][Ti2(BH4)5(PMe2Ph)4], Ti(BH4)3 (PMe2Ph)2, and Ti(BH4)3(PEt3)2," Inorg. Chem. 2006, 45, 1380. Link to pdf.

149. Yang, Y.; Jayaraman, S.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "Crystalline Texture in Hafnium Diboride Thin Films Grown by Chemical Vapor Deposition," J. Cryst. Growth 2006, 294, 389. Link to pdf.

150. Dickinson, P. W.; Girolami, G. S. "Synthesis, Characterization, and X-ray Crystal Structure of the Octabromodiosmate(III) Salt [(C5Me4H)2OsBr]2[Os2Br8] and its Conversion to [(C5Me 4H)2OsBr]­[Os2HBr4(cod)2]," J. Organomet. Chem. 2006, 691, 2883. Link to pdf.

151. Dickinson, P. W.; Girolami, G. S. "Synthesis and Characterization of Osmium(II) Trispyrazolylborate Complexes," Inorg. Chem. 2006, 45, 5215. Link to pdf.

152. Yang, Y.; Jayaraman, S.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "CVD Growth Kinetics of HfB2 Thin Films from the Single Source Precursor Hf(BH4)4," Chem. Mater. 2006, 18, 5088. Link to pdf.

153. Brumaghim, J. L.; Gross, C. L.; Girolami, G. S. "Synthesis, Characterization, and Crystal Structures of the Osmium Triflate Complexes Cp*Os(P-P)(OTf) and [Cp*Os(P-P)(OH2)][OTf]," J. Organomet. Chem. 2006, 691, 3874. Link to pdf.

154. Kim, D. Y.; Girolami, G. S. "Synthesis and Characterization of the Octahydrotriborate Complexes Cp*V(B3 H8)2 and Cp*Cr(B3H8)2, and the Unusual Cobaltaborane Cluster Cp* 2Co2(B6H14)," J. Am. Chem. Soc. 2006, 128, 10969. Link to pdf.

155. Gross, C. L.; Girolami, G. S. "Synthesis and Characterization of Osmium(IV) Polyhydride Complexes of Stoichiometry (C5 Me5)OsH3(L). Crystal Structures of (C5Me5)OsH3(AsPh3) and ( C5Me5)OsH3(PPh3)," Organometallics 2006, 25, 4792. Link to pdf.

156. Noh, W. T.; Girolami, G. S. "Rhenium Oxohalides. Synthesis and Crystal Structures of ReO3Cl(THF)2, ReOCl4(THF), Re2O3Cl6(THF)2, and Re2O3Cl 6(H2O)2," Dalton Trans. 2007, 674. Link to pdf.

157. Yang, Y.; Jayaraman, S.; Sperling, B.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "In-Situ Spectroscopic Ellipsometry Analyses of Hafnium Diboride Thin Films Deposited by Single-Source Chemical Vapor Deposition," J. Vac. Sci. Tech. A 2007, 25, 200. Link to pdf.

158. Holmes, S. M.; Whelpley, A. S.; Girolami, G. S. "Nanocomposite of a Chromium Prussian Blue with TiO2. Redox Reactions and the Synthesis of Prussian Blue Molecule-Based Magnets," Polyhedron 2007, 26, 2291. Link to pdf.

159. Gross, C. L.; Girolami, G. S. "Synthesis and Characterization of Osmium Polyhydrides. X-ray Crystal Structures of (C5Me 5)OsH5 and (C5Me5)2Os2H4," Organometallics 2007, 26, 160. Link to pdf.

160. Spencer, M. D.; Shelby, Q. D.; Girolami, G. S. "Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Si-H•••Ti Interactions," J. Am. Chem. Soc. 2007, 129, 1860. Link to pdf.

161. Gross, C. L.; Brumaghim, J. L.; Girolami, G. S. "Synthesis and Reactivity of the Osmium(III) Pentamethylcyclopentadienyl Complex (C5Me5)2Os2Br4. X-ray Crystal Structures of (C5Me5) 2Os2Br4, (C5Me5)2Os2(μ-O)Br4, and (C5Me5)2Os2(μ-NPh)2Br2," Organometallics 2007, 26, 2258. Link to pdf.

162. Gross, C. L.; Girolami, G. S. "Synthesis and NMR Studies of [(C5Me5)Os(L)H2(H2) +] Complexes. Evidence of the Adoption of Different Structures by a Dihydrogen Complex in Solution and the Solid State," Organometallics 2007, 26, 1658. Link to pdf.

163. Harada, Y.; Girolami, G. S. "Synthesis and Crystal Structures of the Chromium(II) and Chromium(III) Hexafluoroacetylacetonate Complexes trans-Cr(hfac)2(thf)2 and Cr(hfac)3," Polyhedron 2007, 26, 1758. Link to pdf.

164. Goedde, D. M.; Windler, G. K.; Girolami, G. S. "Synthesis and Characterization of the Homoleptic Octahydrotriborate Complex Cr(B3H8)2 and its Lewis Base Adducts," Inorg. Chem. 2007, 46, 2814. Link to pdf.

165. Noh, W. T.; Girolami, G. S. "X-ray Crystal Structure of the Tetra(tert-butyl)erbate Anion and Attempts to Prepare Tetravalent Organolanthanide Complexes," Polyhedron 2007, 26, 3865. Link to pdf.

166. Kumar, N.; Yang, Y.; Noh, W. T.; Girolami, G. S.; Abelson, J. R. "Titanium Diboride Thin Films By Low Temperature Chemical Vapor Deposition from the Single Source Precursor Ti(BH4)3(1,2 Dimethoxyethane)," Chem. Mater. 2007, 19, 3802. Link to pdf.

167. Lazarz, T. S.; Yang, Y.; Kumar, N.; Kim, D. Y.; Noh, W.; Girolami, G. S.; Abelson, J. R. "Low Temperature CVD of Ru from C6H8Ru(CO)3," Mater. Res. Soc. Symp. Proc. 2007, 990, 103. Link to pdf.

168. Kim, D. Y.; Yang, Y.; Abelson, J. R.; Girolami, G. S. "Volatile Magnesium Octahydrotriborate Complexes as Potential CVD Precursors to MgB2. Synthesis and Characterization of Mg(B3H8)2 and its Etherates," Inorg. Chem. 2007, 46, 9060. Link to pdf.

169. Noh, W.; Girolami, G. S. "Synthesis and Characterization of the Cycloheptatrienyl Tantalum Mixed Sandwich Compounds (C5 R5)Ta(C7H7)," Inorg. Chem. 2008, 47, 535. Link to pdf.

170. Jeffries, P. M.; Ellenwood, R. E.; Girolami, G. S. "Anionic Ruthenium(II) Alkyls with Ancillary Diene and Dienyl Ligands: Synthesis and Structures of [(η22-C7H8)RuMe4]2- and [(η 32-C8H11)RuMe3]2-," Inorg, Chim. Acta, 2008, 361, 3265. Link to pdf.

171. Morse, P. M.; Shelby, Q. D.; Kim, D. Y.; Girolami. G. S. "Ethylene Complexes of the Early Transition Metals. Crystal Structures of [HfEt4(C2H4)2-] and the Negative Oxidation State Species [TaHEt(C2H4) 33-] and [WH(C2H4)43-]," Organometallics, 2008, 27, 984. Link to pdf.

172. Kim, D. Y.; You, Y.; Girolami, G. S. "Synthesis and Crystal Structures of Two (Cyclopentadienyl)titanium(III) Hydroborate Complexes, [Cp*TiCl(BH4)]2 and Cp2Ti(B3H8)," J. Organomet. Chem., 2008, 693, 981. Link to pdf.

173. You, Y.; Girolami, G. S. "Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Oligomerization Catalysis," Organometallics, 2008, 27, 3172. Link to pdf.

174. Noh, W.; Girolami, G. S. "Mono(cycloheptatrienyl) Tantalum Chemistry: Synthesis and Characterization of New Tantalum Halide, Hydride, and Alkyl Species." Inorg. Chem., 2008, 47, 10682. Link to pdf.

175. Kumar, N.; Yanguas-Gil, A.; Daly, S. R.; Girolami, G. S,; Abelson, J. R. "Growth Inhibition to Enhance Conformal Coverage in Thin Film Chemical Vapor Deposition" J. Am. Chem. Soc., 2008, 130, 17660. Link to pdf.

176. Reiff, W. M.; Schulz, C. E.; Whangbo, M.; Seo, J. I.; Yoon, S.; Potratz, G. R.; Spicer, C. W.; Girolami, G. S. "Consequences of a Linear Two-Coordinate Geometry for the Orbital Magnetism and Jahn-Teller Distortion Behavior of the High Spin Iron(II) Complex Fe[N(t-Bu)2]2." J. Am. Chem. Soc., 2009, 131, 404. Link to pdf.

177. Bellott, B. J.; Girolami, G. S.; "Structures and Properties of Copper Alkene Complexes. Preorganization Effects and the Binding of Different Isomers of Cyclododecatriene to Copper Triflate." Organometallics, 2009, 28, 2046. Link to pdf.

178. Bellott, B. J.; Noh, Wontae; Nuzzo, Ralph G.; Girolami, G. S.; "Nanoenergetic Materials: Boron Nanoparticles from the Pyrolysis of Decaborane and their Functionalisation.: Chem. Comm., 2009, 22, 3214. Link to pdf.

179. Girolami, G. S. "Origin of the Terms 'Pnictogen' and 'Pnictide'," J. Chem. Educ. 2009, 86, 1200. (Highlighted in Jacobsen, E. K. J. Chem. Educ. 2009, 86, 1154). Link to pdf.

180. Menard, L. D.; Wang, Q.; Kang, J. H.; Sealey, A. J; Girolami, G. S.; Teng, X.; Frenkel, A. I.; Nuzzo, R. G. "Structural Characterization of Bimetallic Nanomaterials with Overlapping X-ray Absorption Edges," Phys. Rev. B, 2009, 80, 064111. (Reprinted in Virtual J. Nanoscale Sci. & Technol. 2009, 20(11)). Link to pdf.

181. Kumar, N.; Yanguas-Gil, A.; Daly, S. R.; Girolami, G. S.; Abelson, J. A. "Remote Plasma Treatment of Si Surfaces: Enhanced Nucleation in Low-Temperature CVD," Appl. Phys. Lett. , 2009, 95, 144107. Link to pdf.

182. Kumar, N.; Noh, W. T.; Daly, S.; Girolami, G. S.; Abelson, J. R. "Low Temperature Chemical Vapor Deposition of Hafnium Nitride-Boron Nitride Nanocomposite Films," Chem. Mater., 2009, 21, 5601. Link to pdf.

183. Flener, C. E.; Woon, D. E.; Dunning, T. H.; Girolami, G. S. "A DFT and ab initio Benchmarking Study of Metal-Alkane Interactions and the Activation of Carbon-Hydrogen Bonds," J. Chem. Phys. B. 2010, 114, 1843. Link to pdf.

184. Daly, S. R.; Girolami, G. S. "Uranium-Hydrogen Interactions. Synthesis and Crystal Structures of Tris(N,N-dimethylaminodiboranato)uranium(III)," Chem. Commun. 2010, 49, 407. Link to pdf.

185. Daly, S. R.; Piccoli, P. M. B.; Schultz, A. J.; Todorova, T. K.; Gagliardi, L.; Girolami, G. S. "Synthesis and Properties of a Fifteen Coordinate Complex: the Thorium Aminodiboranate Th(H3BNMe2BH3)4," Angew. Chem. 2010, 49, 3379. Link to pdf. (Highlighted in Science 2010, 328, 18; Chem. Eng. News 2010, 88(14), 8; and Chemistry World 2010, 7(5), 31.)

186. Daly, S. R.; Kim, D. Y.; Yang, Y.; Abelson, J. R.; Girolami, G. S. "Lanthanide N,N-Dimethylaminodiboranates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films," J. Am. Chem. Soc. 2010, 132, 2106. Link to pdf.

187. Kim, D. Y.; Girolami, G. S. "Highly Volatile Magnesium Complexes with the Aminodiboranate Anion, a New Chelating Borohydride. Synthesis and Characterization of Mg(H3BNMe2BH3)2 and Related Compounds," Inorg. Chem. 2010, 49, 4942. Link to pdf.

188. Daly, S. R.; Girolami, G. S. "Synthesis, Characterization, and Structures of Uranium(III) N,N-Dimethylaminodiboranates," Inorg. Chem. 2010, 49, 5157. Link to pdf.

189. Daly, S. R.; Girolami, G. S. "Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N,N-Dimethylaminodiboranates," Inorg. Chem. 2010, 49, 4578. Link to pdf.

190. Daly, S. R.; Bellott, B. J.; Kim, D. Y.; Girolami, G. S. "Synthesis of the Long-Sought Unsubstituted Aminodiboranate Na(H3BNH2BH3) and its N-Alkyl Analogues," J. Am. Chem. Soc. 2010, 132, 7254. Link to pdf.

191. Dunbar, A. C.; Gozum, J. E.; Girolami, G. S. "Synthesis and Characterization of Phosphine Adducts of Thorium Borohydride, Th(BH4)4. Crystal Structures of Th(BH4)4(PEt3)2 and Th(BH4)4(Me2PCH2CH2PMe2)2," J. Organomet. Chem. 2010, 695, 2804. Link to pdf.

192. Ye, W.; Peña Martin, P. A.; Kumar, N.; Daly, S. R. Rockett, A. A.; Abelson, J. A.; Girolami, G. S.; Lyding, J. W. "Direct Writing of Sub-5 nm Hafnium Diboride Metallic Nanostructures," ACS Nano 2010, 4, 6818. Link to pdf.

193. Piccoli, P. M. B.; Schultz, A. J.; Todorova, T. K.; Gagliardi, L.; Daly, S. R.; Girolami, G. S. "Big Metals, Small Ligands: Characterization of the 15-Coordinate Complex Thorium Aminodiboranate [Th(H3BN(CH3)2BH3)4] by Single Crystal Neutron Diffraction," Am. Cryst. Assn. Symp. Trans. 2010, TR.01.3. Link to pdf.

194. Flener-Lovitt, C., Frenking, G.; Girolami, G. S. "Donor-Acceptor Properties of Bidentate Phosphines. A DFT Study of Nickel Carbonyls and Molecular Dihydrogen Complexes," Organometallics 2012, 31, 4122. Link to pdf.

195. Schmucker, S. W.; Kumar, N.; Abelson, J. R.; Daly, S. R.; Girolami, G. S.; Bischof, M. R.; Jaeger, D. L.; Reidy, R. F.; Gorman, B. P.; Alexander, J.; Ballard, J.; Randall, J.; Lyding, J. W. "Field-Directed Sputter Sharpening for Tailored Probe Materials and Atomic-Scale Lithography," Nature Commun. 2012, 3, 935. Link to pdf.

196. Daly, S. R.; Bellott, B. J.; Nesbit, M. A.; Girolami, G. S. "Synthesis and Structural Diversity of Barium N,N-Dimethylaminodiboranates," Inorg. Chem. 2012, 51, 6449. Link to pdf.

197. Daly, S. R.; Kim, D. Y.; Girolami, G. S. "Lanthanide N,N-Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors," Inorg. Chem. 2012, 51, 7050. Link to pdf.

198. Daly, S. R.; Ephrikhine, M.; Girolami, G. S. "Crystal Structure of the Uranium Oxo Borohydride Complex U2(μ-O)(BH4)6(dme)2 (dme = 1,2-dimethoxyethane) and Reformulation of U2(μ-H)2(BH4)6(dme)2," Polyhedron 2012, 33, 41. Link to pdf.

199. Spicer, C. W.; Flener-Lovitt, C. E.; Girolami, G. S. "Non-Agostic M···H-C Interactions. Synthesis, Characterization, and DFT Study of the Titanium Amide Ti2Cl6[N(t-Bu)2]2," Organometallics 2012, 31, 4894. Link to pdf.

200. Girolami, G. S. "Osmium Weighs In," Nature Chemistry 2012, 4, 954. Link to pdf.

201. Vlaisavljevich, B.; Miró, P.; Koballa, D.; Todorova, T. K.; Daly, S. R.; Girolami, G. S.; Cramer, C. J.; Gagliardi, L. "Volatilities of Actinide and Lanthanide N,N-Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study," J. Phys. Chem. C 2012, 116, 44, 23194. Link to pdf.

202. Shen, L. J.; Gray, D.; Girolami, G. S. "Synthesis and Characterization of a Zinc Metal-Organic Framework with Chiral Nano-Pores," Cryst. Eng. Comm. 2012, 14, 5145. Link to pdf.

203. Nesbit, M. A.; Gray, D. L.; Girolami, G. S. "Bis(benzyl-(μ2-bromo)-diethyl ether-magnesium)," Acta Crystallogr. E 2012, 68, m942. Link to pdf.

204. Do, J.-W.; Estrada, D.; Xie, X.; Chang, N. N.; Girolami, G. S.; Rogers, J. A.; Pop, E.; Lyding, J. W. "Nanosoldering Carbon Nanotube Junctions with Metal via Local Chemical Vapor Deposition for Improved Device Performance," Proc. 12th IEEE Conf. Nanotech. 2012, 1. Link to pdf.

205. Babar, S.; Kumar, N.; Zhang, P.; Dunbar, A. C.; Daly, S. R.; Girolami, G. S.; Abelson, J. R. "Growth Inhibitor to Homogenize Nucleation and Obtain Smooth HfB2 Thin Films by Chemical Vapor Deposition," Chem. Mater. 2013, 25, 662. Link to pdf.

206. Spicer, T. S.; Spicer, C. W.; Cloud, A. N.; Davis, L. M.; Girolami, G. S.; Abelson, J. R. "Low-temperature CVD of η-Mn3N2-x from Bis[di(tert-butyl)amido]manganese(II) and Ammonia," J. Vac. Sci. Technol. A. 2013, 31(3), 030604. Link to pdf.

207. Wang, W. B.; Yanguas-Gil, A.; Yang, Y.; Chang, N. N.; Girolami, G. S.; Abelson, J. R. "Highly Conformal Magnesium Oxide Thin Films by Low-Temperature Chemical Vapor Deposition from Mg(H3BNMe2BH3)2 and Water," Appl. Phys. Lett. 2013, 102, 101605. Link to pdf.

208. Shen, L. J.; Wu, T. J.; Gray, D. L.; Girolami, G. S.; Masel, R. I. "Luminescent Metal-Organic Framework (MOF) Materials as Smart Dusts for the Standoff Detection of Explosives," Chem. Commun. 2013, submitted.

209. Arpin, K. A.; Losego, M. D.; Cloud, A. N.; Ning, H.; Mallek, J.; Sergeant, N. P.; Zhu, L X..; Yu, Z. F.; Kalanyan, B.; Parsons, G. N.; Girolami, G. S.; Abelson, J. R.; Fan, S. H.; Braun, P. V. "Three Dimensional Self-Assembled Photonic Crystals with High Temperature Stability for Thermal Emission Modification," Nature Commun. 2013, accepted.

210. Do, J.-W.; Estrada, D.; Xue, X.; Chang, N.; Girolami, G. S.; Rogers, J. A.; Pop, E.; Lyding, J. W. "Nanosoldering Carbon Nanotube Junctions with Metal via Local Chemical Vapor Deposition for Improved Device Performance," Nano Letters 2013, submitted.

211. Dunbar, A. C.; Macor, J. A.; Girolami, G. S. "Synthesis and Single Crystal Structure of Sodium Octahydrotriborate, NaB3H8," Inorg. Chem. 2013, submitted.

212. Chang, N. N.; Daly, S. R.; Girolami G. S. "Salt Elimination Reactions Do Not Always Eliminate. Mechanistic Study of the Reaction of NdCl3 with Sodium N,N-Dimethylaminodiboranate," Inorg. Chem. 2013, submitted.

213. Gross, C. L.; Brumaghim, J. L.; Jefferis, J. M.; Dickinson, P. W. "Mono(pentamethylcyclopentadienyl) Complexes of Osmium," Inorg. Synth. 2014, in press.


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