Journal Articles (2009 - 2012)
2012
"Mixed-Valence Nickel-Iron Dithiolates Models of the Active Site of the [NiFe]-Hydrogenases", D. Schilter, M. J. Nilges, M. Chakrabarti, P. A. Lindahl, T. B. Rauchfuss, M. Stein, Inorg. Chem., 2012, 51, 2338-48.
"Combining Acid-Base, Redox, and Substrate Binding Functionalities to Give a Complete Model for the [FeFe]-Hydrogenase", J. M. Camara, T. B. Rauchfuss, Nature-Chemistry, 2012, 26-30.
2011
"Influence of Second Coordination Sphere Hydroxyl Groups on the Reactivity of Copper(I) Complexes", C. S. Letko, T. B. Rauchfuss, D. L. Gray, submitted.
"Protonation-Enhanced Lewis Acidity of Iridium Complexes Containing Non-Innocent Amidophenolates", M. R. Ringenberg, T. B. Rauchfuss, Eur. J. Inorg. Chem., 2011, 000.
"Under Sulfur's Spell," T. B. Rauchfuss, Nature-Chemistry, 2011, 3, 648.
"Active-Site Models for the Nickel-Iron Hydrogenases: Effects of Ligands on Reactivity and Catalytic Properties", M. E. Carroll, B. E. Barton, D. E. Gray, A. Mack, T. B Rauchfuss, Inorg. Chem., 2011, 50, 9554–9563.
"A New Route to Azadithiolato Complexes", R. Angamuthu, M. E. Carroll, M. Ramesh, T. B. Rauchfuss, Eur. J. Inorg. Chem., 2011, 1029-1032.
"Oxidative Addition of a Diphosphine-Anhydride to Fe(0) and Ni(0): A Simple Approach to Installing Four Ligands", M. R. Ringenberg, D. L. Gray, T. B. Rauchfuss, Organometallics, 2011, 30, 2885-2888.
"Coordination Chemistry of the Soft Chiral Lewis Acid [Cp*Ir(TsDPEN)]", C. S. Letko, Z. H. Heiden, T. B. Rauchfuss, Inorg. Chem. 2011, 50, 5558-5566.
"Stereochemistry of Electrophilic Attack at 34e- Dimetallic Complexes: The Case of Diiron Dithiolato Carbonyls + SMe+", M. T. Olsen, D. L. Gray, T. B. Rauchfuss, L. De Gioia, G. Zampella, Chem. Comm. 2011, 47, 6554-6556.
"Mild Redox Complementation Enables H2 Activation by [FeFe]-Hydrogenase Models", J. M. Camara, T. B. Rauchfuss, J. Am Chem. Soc. 2011, 133, 8098-8101.
"Dioxygen and Hydrogen Peroxide Reduction with Hemocyanin Model Complexes", M. A.. Thorseth, C. S. Letko, T. B. Rauchfuss, A. A. Gewirth, Inorg. Chem. 2011, 50, 6158-6161.
2010
"Organoiridium Pyridonates and Their Role in the Dehydrogenation of Alcohols" A. M. Royer, Thomas B. Rauchfuss, D. Gray, Organometallics, 2010, 29, 6763–6768.
"Iron Acyl Thiolato Carbonyls: Structural Models for the Active Site of the [Fe]-Hydrogenase (Hmd)" A. M. Royer, T. B. Rauchfuss, M. Salomone-Stagni, W. Meyer-Klaucke, 2010, 132,16997–17003.
"Efficient Route to Hydroxymethylfurans from Sugars via Transfer Hydrogenation" T. Thananatthanachon, T. B. Rauchfuss, ChemSussChem, 2010, 3, 1139–1141.
"Hydride-Containing Models for the Active Site of the Nickel-Iron Hydrogenases" B. E. Barton, T. B. Rauchfuss, J. Am Chem. Soc. 2010, 132, 14877–14885.
"Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications" M. T. Olsen, T. B. Rauchfuss, S. R. Wilson, J. Am Chem. Soc., 2010, 132, 17733–17740.
"Artificial Hydrogenases" B. E. Barton, M. T. Olsen, T. B. Rauchfuss, Current Opinion in Biotechnology, 2010, 21, 292-297.
"Efficient Production of the Liquid Fuel 2,5-Dimethylfuran from Fructose Using Formic Acid as a Reagent" T. Thananatthanachon, T. B. Rauchfuss, Angew. Chem. Int. Ed. 2010, 49, 6616–6618.
"Isomerization of the Hydride Complexes [HFe2(SR)2(PR)x(CO)6-x]+ (x = 2, 3, 4) Relevant to the Diiron Center in the [FeFe]-Hydrogenases" Bryan E. Barton, Giuseppe Zampella, G.; Aaron K. Justice, L.De Gioia, T. B. Rauchfuss, S. R. Wilson, J. Chem. Soc. Dalton Trans. 2010, 39, 3011-3019.
"The Electronic structure of [Fe]-Hydrogenase and Model Systems: an X-ray Absorption Near Edge Spectroscopy Study" M. Salomone-Stagnia, F. Stellato, C. M. Whaley, S. Vogt, Bill E. Morante, S. Shima, T. B. Rauchfuss, W. Meyer-Klaucke, J. Chem. Soc. Dalton Trans. 2010, 39, 3057-3064.
"Oxidation of Dihydrogen by Iridium Complexes of Redox-active Ligands" M. R. Ringenberg, M. J. Nilges, T. B. Rauchfuss, S. R. Wilson, Organometallics, 2010, 29, 1956–1965. Inorganic Syntheses, volume XXXV. Rauchfuss, T. B. (editor), John Wiley, 2010.
2009
"Isomerization of the Hydride Complexes [HFe2(SR)2(PR)x(CO)6-x]+ (x = 2, 3, 4) Relevant to the Diiron Center in the [FeFe]-Hydrogenases" Bryan E. Barton, G. Giuseppe Zampella, Aaron K. Justice, L. De Gioia, T. B. Rauchfuss, S. R. Wilson, J. Chem. Soc. Dalton Trans. 2009, 29, 1956-1965.
"Activation and Deactivation of Cp*Ir(TsDPEN) Hydrogenation Catalysts in Water" C. S. Letko, Z. M. Heiden, T. B. Rauchfuss, Eur. J. Inorg. Chem., 2009, 4927-4930.
"Oxidative Addition of Thioesters to Fe(0): Active-Site Models For Hmd, Nature’s Third Hydrogenase" A. M. Royer, T. B. Rauchfuss, and D. L. Gray Organometallics, 2009, 28, 3618-3620.
"Nickel-Iron-Dithiolato-Hydrides Relevant to the [NiFe]-Hydrogenase Active Site" B. E. Barton, C. M. Whaley, T. B. Rauchfuss, D. L. Gray, J. Am Chem. Soc., 2009 131, 6942–6943.
"Proton-Assisted Activation of Dihydrogen: Mechanistic Aspects of Proton-Catalyzed Addition of H2 to Ru and Ir Amido Complexes," Z. M. Heiden, T. B. Rauchfuss, J. Am Chem. Soc. 2009, 131, 3593-3600.
"π-Complexes of Lignols with Mn(I) and Ru(II)," D. Morvan, T. B. Rauchfuss, S. R. Wilson, Organometallics 2009, 28, 3161–3166.
"Coordination Chemistry of [HFe(CN)2(CO)3]- and Its Derivatives: Toward a Model for the Iron Subsite of the [NiFe]-Hydrogenases," C. M. Whaley, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem. 2009, 49, 4462-4469.
"Redox-Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands", J. L. Boyer, T. Cundari, N. J. DeYonker, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem., 2009, 49, 638-645.
"Small Molecule Mimics of Hydrogenase: Hydrides and Redox," F. Gloaguen, T. B. Rauchfuss Chem. Soc. Rev., 2009, 38, 100-108.