Journal Articles (1999-2003)
2003
"Electrosynthesis of ReS4. XAS Analysis of ReS2, Re2S7, and ReS4" Schwarz, D. E.,: Frenkel, A. E.; Nuzzo, R. G.; Rauchfuss, T. B.; Vairavamurthy, A. Chem. Mater. 2003, 16, 151-158
"Protonation Studies of the New Iron Carbonyl Cyanide trans-[Fe(CO)3(CN)2]2-: Implications with Respect to Hydrogenases" Kayal, A.; Rauchfuss, T. B., Inorg. Chem. 2003, 42, 5046-8.
"Structural Chemistry of "Defect" Cyanometallate Boxes {Cs[(C5R5)M(CN)3]4[Cp*Ru]3} (M = Co, R = H; M = Rh, R = Me)" Kuhlman, M. L.; Rauchfuss, T. B.; Wilson, S. R. J. Am. Chem. Soc. 2003, 124, 10084-92.
"Structural Analogues of the Bimetallic Reaction Center in Acetyl CoA Synthase: A Ni-Ni Model with Bound CO" Linck, R. C.; Spahn, C. W.; Rauchfuss, T. B.; Wilson, S. R., J. Am. Chem. Soc. 2003, 124, 8700-1.
"Synthesis of Transition Metal Dithiolenes", Rauchfuss, T. B., Prog. Inorg. Chem. 2003, 52, 1-54.
"Ruthenium Derivatives of NiS2N2 Complexes as Analogues of Bioorganometallic Reaction Centers" Reynolds, M. A.; Rauchfuss, T. B.; Wilson, S. R., Organometallics 2003, 22, 1619-1625.
"Aggregation of PMe3-Stabilized Molybdenum Sulfides and the Catalytic Dehydrogenation of H2S" Schwarz, D. E.; Rauchfuss, T. B.; Wilson, S. R., Inorg. Chem. 2003, 42, 2410-17.
"Membership Rules for a Molecular Box: the Admission Process and Protection Provided to Guest Molecules", Hsu, S. C. N.; Ramesh, M.; Espenson, J. H.; Rauchfuss, T. B., Angew. Chem. Int. Ed. 2003, 42, 2663-6.
2002
"New Class of Diiron Dithiolates Related to the Fe-Only Hydrogenase Active Site: Synthesis and Characterization of [Fe2(SR)2(CNMe)7]2+" Lawrence, J. D.; Rauchfuss, T. B.; Wilson, S. R., Inorg. Chem. 2002, 41, 6193-5.
"Bimetallic Carbonyl Thiolates as Functional Models for the Fe-only Hydrogenases", Gloaguen, F.; Lawrence, J. D.; Rauchfuss, T. B.; Bénard, M.; Rohmer, M.-M., Inorg. Chem. 2002, 41, 6573-82.
"An Organometallic Route to Oligonucleotides Containing Phosphoselenoate", Holloway, G. A.; Pavot, C.; Scaringe, S. A.; Lu, Y.; Rauchfuss, T. B., ChemBioChem. 2002, 3, 1061-65.
"Systematic Assembly of the Double Molecular Boxes: {Cs[CpCoCN3]4[Cp*Ru]3} as a Tridentate Ligand," Contakes, S. M.; Kuhlman, M. L.; Ramesh, M.; Wilson, S. R.; Rauchfuss, T. B., Proc. Nat. Acad. Sci. USA, 2002, 99, 4889-4893.
"New Class of Ruthenium Sulfide Clusters: Ru4S6(PPh3)4, Ru5S6(PPh3)5, and Ru6S8(PPh3)6", Eckermann, A. L.; Wunder, M.; Fenske, D.; Rauchfuss, T. B.; Wilson, S. R., Inorg. Chem., 2002, 41, 2004-2006.
"Preparative and Structural Studies
on the Carbonyl Cyanides of Iron, Manganese, and Ruthenium: Fundamentals Relevant
to the Hydrogenases," Contakes, S. M.; Hsu, S. C. N.; Rauchfuss,
T. B.; Wilson, S. R., Inorg. Chem., 2002, 41, 1670-1678.
"Iron Carbonyl Sulfides, Formaldehyde, and Amines Condense to Give the Proposed Azadithiolate Cofactor of the Fe-only Hydrogenases," Li, H. X.; Rauchfuss, T. B., J. Am. Chem Soc., 2002, 124, 726-727.
"(Et4N)ReS4" Goodman, J. T.; Rauchfuss, T. B., Inorg. Synth., 2002, 33, 107-110.
2001
"Synthetic and Structural Studies on [Fe2(SR)2(CN)x(CO)6-x]x- as Analogues of the Fe-only Hydrogenases" Gloaguen, F.; Lawrence, J. D.; Schmidt, M.; Wilson, S. R.; Rauchfuss, T. B., J. Am. Chem Soc., 2001, 123, 12518-12527.
"Biomimetic Proton Reduction Catalyzed by an Iron Carbonyl Thiolate" Gloaguen, F.; Lawrence, J. D.; Rauchfuss, T. B., J. Am. Chem. Soc. 2001, 123, 9476-9477.
"Beyond Fe-only Hydrogenases: N-Functionalized
2-Aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x
( x = 5, 6)", Lawrence, J. D.; Li, H.; Rauchfuss, T. B., Chem.
Commun. 2001, 1483-4.
"Heterolytic and Homolytic Activation of Hydrogen at an Unusual Iridium(II) Sulfide" Linck, R. C.; Pafford, R. J.; Rauchfuss, T. B., J. Am. Chem. Soc. 2001, 123, 8856-8857.
"The Influence of Cyanide on the Carbonylation of Iron(II): Synthesis of Fe-SR-CO-CN Centers Related to the Hydrogenase Active Sites" Rauchfuss, T. B.; Contakes, S. M.; Hsu, S. C. N.; Reynolds, M. A.; Wilson, S. R., J. Am. Chem. Soc. 2001, 123, 6933-4.
"Re(SH)2H(PMe3)4: a Catalyst for Fundamental Transformations Involving H2 and H2S" Schwarz, D. E.; Dopke, J. A.; Rauchfuss, T. B.; Wilson, S. R., Angew. Chem. Int. Ed. 2001, 40, 2351-2353.
"Diiron Azadithiolates: Synthesis, Structure, and Stereoelectronics" Lawrence, J. D.; Li, H.; Rauchfuss, T. B.; Bénard, M.; Rohmer M.-M., Angew. Chem. Int. Ed. 2001, 40, 1768-71.
"Synthesis of Ru-S Clusters with Kinetically Labile Ligands via the Photolysis of [(cymene)3Ru3S2](PF6) 2" Eckermann, A. L.; Fenske, D.; Rauchfuss, T. B., Inorg. Chem. 2001, 40, 1459-1465.
"Alkali Metal Templated Assembly of the Tetrahedral Cyanometallate Cages (Et4N)5[M@Mo4(µ-CN)6 (CO)12 ](M = Li, Na)" Contakes, S. M.; Rauchfuss, T. B., Chem. Commun. 2001, 553-4.
"Redox Properties of C6S8n— and C3S5n— (n = 0, 1, 2): Stable Radicals and Unusual Structural Properties for C—S—S—C Bonds" Breitzer, J. G.; Smirnov, A. I.; Szczepura, L. F.; Wilson, S. R.; Rauchfuss, T. B. Inorg. Chem. 2001, 40, 1421-1429.
2000
"Aufbau Approach to Multimetallic Ensembles Based on Tetrathiooxalate: [Cp*4Rh4(C2S4)2]2+,[Cp*3RuRh2(C2S4)]+, and [Cp*6Rh6(C2S4)2]4+" Holloway, G. A.; Klausmeyer, K. K.; Rauchfuss, T. B. Organometallics 2000, 19, 5370-5.
"The N-H—S Hydrogen Bond in (TACN)2Fe2S6(TACN = triazacyclononane) and in Model Systems Involving the Persulfido Moiety. An Ab Initio and DFT Study" François, S.; Rohmer, M.-M.; Bénard, M.; Moreland, A. C.; Rauchfuss, T. B. J. Am. Chem. Soc. 2000, 122, 12743-50.
"Rubber Compositions Containing Zinc Hexasulfido Complexes" U. S. Patent No. 6,114,469 with Mander, E. O.; Ignatz-Hoover, F. assigned to Flexsys America, L. P. 2000 (international patent number 99939085.9-2102).
"pi-Complexes of Phthalocyanines and Metallophthalocyanines" Contakes, S. M.; Beatty, S. T.; Dailey, K. K.; Rauchfuss, T. B.; Fenske, D. Organometallics 2000, 19, 4767-74.
"The Addition of Isocyanides to ReS4-: [3 + 1] Cycloaddition to S=M=S" Schwarz, D. E.; Rauchfuss, T. B. Chem. Commun. 2000, 1123-1124.
"A Trigonal Prismatic Cyanometallate Cage: [K@Mo6(µ-CN)9(CO)18]8-" Contakes, S. M.; Rauchfuss, T. B. Angew. Chem., Int. Ed. 2000, 39, 1984-1986.
"Studies on alpha-C3S52- (dmit2-) and Its Dinuclear Ni(II) Complex: Spectroscopic and Structural Characterization" Breitzer, J. G.; Rauchfuss, T. B., Polyhedron 2000, 19, 1283-1291.
"Binding of pi-Acceptor Ligands to Triamine Iron(II) Complexes" Moreland, A. C.; Rauchfuss, T. B. Inorg. Chem. 2000, 39, 3029-36.
"Coordination Solids Derived from Cp*M(CN)3- (M = Rh, Ir)" Contakes, S. M.; Klausmeyer, K. K.; Rauchfuss, T. B. Inorg. Chem. 2000, 39, 2069-2075.
"Rubber Compositions Containing Zinc Hexasulfido Complexes" Rauchfuss, T. B.; Maender, O. W.; Ignatz-Hoover, F. U.S. Patent 2000, 6,114,469.
"Influence of H2S and Thiols on the Binding of Alkenes and Alkynes to ReS4-: The Spectator Sulfido Effect" Dopke, J. A.; Rauchfuss, T. B., Inorg. Chem. 2000, 39, 5014-21.
1999
"Synthesis and Technique in Inorganic Chemistry, A Laboratory Manual" (3rd Ed) Girolami, G. S.; Rauchfuss, T. B.; Angelici, R. J.; University Science Books: Mill Valley (CA), 1999.
"First Generation Analogues of the Binuclear Site in the Fe-Only Hydrogenases: Fe2(SR)2(CO)4(CN)22-" Schmidt, M.; Contakes, S. M.; Rauchfuss, T. B. J. Am. Chem. Soc. 1999, 121, 9736-9737.
"Third Order-Nonlinear Optical Properties of Sulfur-Rich Compounds"Breitzer, J. G.; Dlott, D. D.; Iwaki, L.; McHugh, S. B.; Rauchfuss, T. B. J. Phys. Chem. 1999, 103, 6930-6937.
"Synthesis of Organometallic Solids by Protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)" Contakes, S. M.; Schmidt, M.; Rauchfuss, T. B. Chem. Commun. 1999, 1183-1184.
"Dehydrogenative Route to Metallo Dithiolenes: The Reaction of Zinc Polysulfides and Alkenes" Pafford, R. J.; Chou, J.-H.; Rauchfuss, T. B. Inorg. Chem. 1999, 38, 3779-3786.
"Direct Observation of Ligand-Centered Redox in Cp*2Rh2(C2S4)Clx (x = 2, 0)" Holloway, G. A.; Rauchfuss, T. B. Inorg. Chem. 1999, 38, 3018-9.
"Binding of Alkenes to ReS4-" Goodman, J. T.; Rauchfuss, T. B. J. Am. Chem. Soc. 1999, 121, 5017-5022.
"Alkali Metal-Templated Asssembly of Cyanometallate Boxes (NEt4)3{M[Cp*Rh(CN)3]4[Mo( CO)3]4} (M = K, Cs): Selective Binding of Cs+" Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. J. Am. Chem. Soc. 1999, 121, 2705-2711.